雙(三苯基膦)疊氮化亞銨

雙(三苯基膦)疊氮化亞銨是一種有機磷化合物,化學式為(C36H30NP2)N3。它可由氨基三苯基疊氮化鏻在200~210 °C熱分解得到,[1]或由雙(三苯基膦)氯化亞銨和鹼金屬疊氮化物的複分解反應製得。[2]它和氫溴酸高氯酸反應,可以得到相應的溴化物或高氯酸鹽。[1]它可用於製備一些疊氮配合物。[3]

雙(三苯基膦)疊氮化亞銨
識別
CAS號 38011-36-8  checkY
SMILES
 
  • [N-]=[N+]=[N-].N(=P(C=1C=CC=CC1)(C=2C=CC=CC2)C=3C=CC=CC3)[P+](C=4C=CC=CC4)(C=5C=CC=CC5)C=6C=CC=CC6
性質
化學式 C36H30N4P2
摩爾質量 580.6 g·mol−1
外觀 無色晶體
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ 1.0 1.1 Cookson, R. C.; Hughes, A. N. Pyrolysis of triphenylphosphiniminium azide. Journal of the Chemical Society, 1963. pp 6061-6062. doi:10.1039/JR9630006039
  2. ^ Martinsen, Arve; Songstad, Jon. Preparation and properties of some bis(triphenylphosphine)iminium salts, [(Ph3P)2N]X. Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1977. 31 (8): 645-650. ISSN 0302-4377.
  3. ^ Haiges, Ralf; Rahm, Martin; Christe, Karl O. Unprecedented Conformational Variability in Main Group Inorganic Chemistry: the Tetraazidoarsenite and -Antimonite Salts A+[M(N3)4] (A = NMe4, PPh4, (Ph3P)2N; M = As, Sb), Five Similar Salts, Five Different Anion Structures. Inorganic Chemistry (American Chemical Society (ACS)). 2012-12-07, 52 (1): 402–414. ISSN 0020-1669. doi:10.1021/ic3021996.