均苯四甲酰氯

化合物

均苯四甲酰氯是一种有机化合物,化学式为C10H2Cl4O4。它可由均苯四甲酸(或均苯四甲酸二酐[3])在N,N-二甲基甲酰胺的催化下于氯化亚砜中回流反应得到。[4]它和正己胺在三氯甲烷中反应,得到四己基均苯四甲酰胺,[5]和其它类发生类似反应。[6]

均苯四甲酰氯
别名 1,2,4,5-苯四甲酰氯
识别
CAS号 7710-20-5  checkY
性质
化学式 C10H2Cl4O4
摩尔质量 327.93 g·mol⁻¹
密度 1.681±0.06 g·cm−3[1]
熔点 63.4—64.2 °C(336.5—337.3 K)[2]
相关物质
相关化学品 苯甲酰氯
对苯二甲酰氯
均苯三甲酰氯
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-7]
  2. ^ Gitina, R. M.; Vasil'eva, I. V.; Zaitseva, E. L.; Teleshov, E. N.; Shifrina, R. R.; Kurkovskaya, L. N.; Pravednikov, A. N.; Botvinnik, E. S.; Shmagina, N. N.; Gefter, E. L. Synthesis of aromatic bis(o-cyano)​dicarboxylic acids. Zhurnal Organicheskoi Khimii, 1976. 12 (9): 1980-1987.
  3. ^ Jing Liu, Rujuan Li, Mengya Guo, Hairong Tao, Donglan Sun, Chengxing Zong, Chunjing Liu, Fengzhi Fu. Study of the thermal degradation of benzene-containing glycerol carbonate derivatives by a combined TG–FTIR and theoretical calculation. Thermochimica Acta. 2017-08, 654: 179–185 [2019-11-07]. doi:10.1016/j.tca.2017.05.021. (原始内容存档于2018-06-28) (英语). 
  4. ^ O. Qanati, A. Ahmadi, M. S. Seyed dorraji, M. H. Rasoulifard, V. Vatanpour. Thin-film nanofiltration membrane with monomers of 1,2,4,5-benzene tetracarbonyl chloride and ethylene diamine on electrospun support: preparation, morphology and chlorine resistance properties. Polymer Bulletin. 2018-08, 75 (8): 3407–3425 [2019-11-07]. ISSN 0170-0839. doi:10.1007/s00289-017-2214-9 (英语). 
  5. ^ Yuichi Sakanishi. Thixotropic agent for use in coating solvent and coating. 2016. JP 2016121272 A
  6. ^ Sakanishi, Yuichi; Saeki, Takashi; Kaide, Aya. Thickening stabilizer which thickens and stabilizes a flowable organic substance and a thickening stabilizing composition containing the same. 2018. WO 2018042933 A1