1,3,5-三(苯乙炔基)苯

1,3,5-三(苯乙炔基)苯是一种有机化合物,化学式为C30H18。它可由三(苯乙炔基)铟和1,3,5-三溴苯Pd(dppf)Cl2催化下反应制得,[1]或由苯乙炔和1,3,5-三溴苯在碘化亚铜Pd(PPh3)2Cl2催化下反应得到。[2]它和八羰基二钴反应可以得到炔烃配合物。[3]

1,3,5-三(苯乙炔基)苯
识别
CAS号 118688-56-5  checkY
性质
化学式 C30H18
摩尔质量 378.46 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Pena, Miguel A.; Pérez Sestelo, José; Sarandeses, Luis A. (2005). New Synthetic Applications of Indium Organometallics in Cross-Coupling Reactions. Synthesis, 2005(3), 485–492. doi:10.1055/s-2004-834945
  2. ^ Jandke, Markus; Strohriegl, Peter; Berleb, Stefan; Werner, Ekkehard; Bruetting, Wolfgang. Phenylquinoxaline Polymers and Low Molar Mass Glasses as Electron-Transport Materials in Organic Light-Emitting Diodes. Macromolecules (1998), 31(19), 6434-6443. doi:10.1021/ma9806054.
  3. ^ Solid-State Pyrolysis of Polyphenylene–Metal Complexes: A Facile Approach Toward Carbon Nanoparticles. Adv. Funct. Mater. 2007. 17 (7): 1179-1187. doi:10.1002/adfm.200600826.