环己基碘

化合物

环己基碘是一种有机化合物,化学式为C6H11I。可由环己醇氢碘酸加热反应制得,[4]或由环己烯碘化氢反应得到[5],反应中的碘化氢可由碘化钾磷酸替代[6]环己基溴和氢碘酸的卤素交换也会生成环己基碘。[7]

环己基碘
英文名 Iodocyclohexane
Cyclohexyl iodide
别名 碘代环己烷
NSC 6075
识别
CAS号 626-62-0  checkY
SMILES
 
  • C1CCCCC1I
性质
化学式 C6H11I
摩尔质量 210.06 g·mol−1
密度 1.624 g·cm−3(20 °C)[1]
熔点 52 °C(325 K)[2]
沸点 180—183 °C(453—456 K)[3]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Arthur I. Vogel. Iodides and bromides from alcohols. 1944. GB 565452.
  2. ^ Robert Truffault. Phosphoric anhydride as a catalyst for the polymerization of unsaturated hydrocarbons. A decahydrobiphenyl obtained by dimerization of cyclohexene. Bulletin de la Societe Chimique de France, Memoires, 1936. 3: 442-459. ISSN: 0366-3132.
  3. ^ B. Lecea, J.M. Aizpurua, C. Palomo. Reagents and synthetic methods 52. Silane reduction of carbonyl compounds in the presence of iodine. Tetrahedron. 1985-01, 41 (20): 4657–4665 [2019-12-04]. doi:10.1016/S0040-4020(01)82361-9 (英语). 
  4. ^ Doya, Masaharu; Hoshino, Yuki. Preparation of iodine compounds by alcohol iodination using hydriodic acid while removing generated water. Jpn. Kokai Tokkyo Koho, 2010. JP 2010159223 A
  5. ^ Breton, Gary W.; Kropp, Paul J.; Harvey, Ronald G. Hydrogen iodide. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001.
  6. ^ IODOCYCLOHEXANE. Organic Syntheses. 1951, 31: 66 [2019-12-04]. doi:10.15227/orgsyn.031.0066. (原始内容存档于2018-06-02). 
  7. ^ Mohammad Namavari, N. Satyamurthy, Michael E. Phelps, Jorge R. Barrio. Halogen exchange reactions between alkyl halides and aqueous hydrogen halides. A new method for preparation of alkyl halides.. Tetrahedron Letters. 1990-01, 31 (35): 4973–4976 [2019-12-04]. doi:10.1016/S0040-4039(00)97781-5. (原始内容存档于2018-07-02) (英语).