四十一烷是一种有机化合物,化学式为C41H84。它是聚丙烯(PP)及高密度聚乙烯英语High-density polyethylene(HPDE)的催化热解产物之一。[3][4]它可以形成正交晶系的晶体,空间群Pbcm[5]它的临界点为922 K、0.809 MPa。[6]

四十一烷
英文名 Hentetracontane
识别
CAS号 7194-87-8  checkY
性质
化学式 C41H84
摩尔质量 577.11 g·mol−1
外观 固体
熔点 84.1 °C(357.2 K)(97%纯度样品)[1]
82.3 °C(355.4 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

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  1. ^ Ahmed Hammami, Anil K. Mehrotra. Non-isothermal crystallization kinetics of n-paraffins: comparison of even-numbered and odd-numbered normal alkanes. Thermochimica Acta. 1993-02, 215: 197–209 [2022-08-17]. doi:10.1016/0040-6031(93)80093-P. (原始内容存档于2018-06-14) (英语). 
  2. ^ H. Kraack, E. B. Sirota, M. Deutsch. Measurements of homogeneous nucleation in normal-alkanes. The Journal of Chemical Physics. 2000-04-15, 112 (15): 6873–6885 [2022-08-17]. ISSN 0021-9606. doi:10.1063/1.481263. (原始内容存档于2022-03-07) (英语). 
  3. ^ M. Ismail Khan, Imtiaz Ahmad, Hizbullah Khan, M. Ishaq, Razia Khan, Kashif Gul, Waqas Ahmad. Catalytic Performance of Metal Impregnated Carbon (Darco) in Conversion of Polypropylene and High-Density Polyethylene into Useful Products. Fullerenes, Nanotubes and Carbon Nanostructures. 2015-07-03, 23 (7): 627–639 [2022-08-17]. ISSN 1536-383X. doi:10.1080/1536383X.2014.945167 (英语). 
  4. ^ Imtiaz Ahmad, Mohammad Ismail Khan, Hizbullah Khan, Mohammad Ishaq, Razia Tariq, Kashif Gul, Waqas Ahmad. Influence of metal-oxide-supported bentonites on the pyrolysis behavior of polypropylene and high-density polyethylene. Journal of Applied Polymer Science. 2015-01-05, 132 (1) [2022-08-17]. doi:10.1002/app.41221. (原始内容存档于2022-08-17) (英语). 
  5. ^ Steven R. Craig, Gerard P. Hastie, Kevin J. Roberts, John N. Sherwood. Investigation into the structures of some normal alkanes within the homologous series C13H28 to C60H122 using high-resolution synchrotron X-ray powder diffraction. Journal of Materials Chemistry. 1994, 4 (6): 977 [2022-08-17]. ISSN 0959-9428. doi:10.1039/jm9940400977 (英语). 
  6. ^ Eric W. Lemmon, A. R. H. Goodwin. Critical Properties and Vapor Pressure Equation for Alkanes CnH2n+2: Normal Alkanes With n⩽36 and Isomers for n=4 Through n=9. Journal of Physical and Chemical Reference Data. 2000-01, 29 (1): 1–39 [2022-08-17]. ISSN 0047-2689. doi:10.1063/1.556054. (原始内容存档于2017-12-20) (英语). 

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