一百烷是一种有机化合物,化学式为C100H202。它可由1-碘代五十烷和金属反应制得,[3]并可在二甲苯中重结晶。[4]它的同分异构体有5.92×1039种。[5]

一百烷
英文名 Hectane
别名 正一百烷
识别
CAS号 6703-98-6  checkY
PubChem 14009497
ChemSpider 20035403
SMILES
 
  • CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC
性质
化学式 C100H202
摩尔质量 1404.67 g·mol−1
外观 晶体
密度 0.836±0.06 g·cm−3(20 °C)[1]
0.846 g·cm−3(20 °C)[2]
熔点 115.1—115.4 °C(388.2—388.5 K)[3]
相关物质
相关化学品 五十烷
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-09-15].
  2. ^ Yuhong Wang, Kecheng Zhao. Different Forms of Asphaltene Microstructures Discovered in Transmission Electron Microscopy. Journal of Materials in Civil Engineering. 2016-11, 28 (11): 04016137 [2020-09-15]. ISSN 0899-1561. doi:10.1061/(ASCE)MT.1943-5533.0001660. (原始内容存档于2021-10-25) (英语). 
  3. ^ 3.0 3.1 Ställberg, Gunnel; Ställberg-Stenhagen, Stina; Stenhagen, Einar; Finsnes, Ernst; Sörensen, Jörgine Stene; Sörensen, Nils Andreas. Very Long Hydrocarbon Chains. I. The Synthesis of n-Dooctacontane and n-Hectane.. Acta Chemica Scandinavica. 1952, 6: 313–326. ISSN 0904-213X. doi:10.3891/acta.chem.scand.06-0313. 
  4. ^ The study of crystal growth with the electron microscope IV. The nucleation and growth of n -propyl n -pentacontanoate. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 1955-03-22, 228 (1175): 539–548 [2020-09-15]. ISSN 0080-4630. doi:10.1098/rspa.1955.0067. (原始内容存档于2019-10-25) (英语). 
  5. ^ Hans Lohninger. List of Alkanes. General Chemistry. 2011-05-20 [2020-09-15]. (原始内容存档于2020-05-27). 

拓展阅读

编辑

  • Hay, J. N. Thermal analysis of n-hectane. Journal of Polymer Science Part B: Polymer Letters. 1970, 8 (6): 395–399. ISSN 0449-2986. doi:10.1002/pol.1970.110080602. 
  • Goncharov, M. A. Number of isomers in some saturated hydrocarbons(俄文). Vestnik Moskovskogo Universiteta, Seriya 4: Geologiya, 1973. 28 (3): 117-118. ISSN: 0579-9406.