4-碘吡啶

化合物

4-碘吡啶是一种有机化合物,化学式为C5H4IN,是碘吡啶德语Iodpyridine的同分异构体之一。它可由4-氨基吡啶反应得到重氮盐后与碘化钾反应得到。[2]4-氯吡啶盐酸盐和碘化钠在乙腈中反应也可以得到4-碘吡啶。[3]它和芳基硼酸在四(三苯基膦)钯的催化下反应,可以得到4-吡啶基芳基化合物。[4]

4-碘吡啶
英文名 4-iodopyridine
识别
CAS号 15854-87-2  checkY
性质
化学式 C5H4IN
摩尔质量 205 g·mol−1
熔点 106—108 °C(379—381 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Yasuyuki Suzuki. Synthesis of 4-Iodopyridine and its Homologs. YAKUGAKU ZASSHI. 1961, 81 (8): 1206–1207 [2020-05-29]. ISSN 0031-6903. doi:10.1248/yakushi1947.81.8_1206. (原始内容存档于2018-06-01) (英语). 
  2. ^ C. Coudret. Efficient Syntheses of 4-Iodopyridine and of 4-Pyridylboronic Acid Pinacol Ester. Synthetic Communications. 1996-10, 26 (19): 3543–3547 [2020-05-29]. ISSN 0039-7911. doi:10.1080/00397919608003763 (英语). 
  3. ^ Pia Bonakdarzadeh, Filip Topić, Elina Kalenius, Sandip Bhowmik, Sota Sato, Michael Groessl, Richard Knochenmuss, Kari Rissanen. DOSY NMR, X-ray Structural and Ion-Mobility Mass Spectrometric Studies on Electron-Deficient and Electron-Rich M 6 L 4 Coordination Cages. Inorganic Chemistry. 2015-06-15, 54 (12): 6055–6061 [2020-05-29]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.5b01082 (英语). 
  4. ^ Andrea Czompa, Balázs László Pásztor, Jennifer Alizadeh Sahar, Zoltán Mucsi, Dóra Bogdán, Krisztina Ludányi, Zoltán Varga, István M. Mándity. Scope and limitation of propylene carbonate as a sustainable solvent in the Suzuki–Miyaura reaction. RSC Advances. 2019, 9 (65): 37818–37824 [2020-05-29]. ISSN 2046-2069. doi:10.1039/C9RA07044C (英语).