3-甲基戊醛

化合物

3-甲基戊醛是一种有机化合物,化学式为C6H12O,它存在S型和R型两种异构。它可由3-甲基戊醇马丁试剂吡啶氯铬酸盐氧化得到。[2][3]它可以被氧化为3-甲基戊酸。[4]

3-甲基戊醛
英文名 3-methylpentanal
识别
CAS号 15877-57-3  checkY
1730-94-5(3S checkY
51468-48-5(3R checkY
性质
化学式 C6H12O
摩尔质量 100.16 g·mol−1
沸点 122 °C(395 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Levene, P. A.; Rothen, Alexandre; Kuna, Martin. Optical rotation of configurationally related aldehydes. Journal of Biological Chemistry, 1935. 111: 739-747.
  2. ^ Saskia Thurnhofer, Walter Vetter. Synthesis of (S)-(+)-enantiomers of food-relevant (n-5)-monoenoic and saturated anteiso-fatty acids by a Wittig reaction. Tetrahedron. 2007-01, 63 (5): 1140–1145 [2022-03-07]. doi:10.1016/j.tet.2006.11.059. (原始内容存档于2018-07-01) (英语). 
  3. ^ Zelong Lim, Peter J. Duggan, Soo San Wan, Guillaume Lessene, Adam G. Meyer, Kellie L. Tuck. Exploiting the Biginelli reaction: nitrogen-rich pyrimidine-based tercyclic α-helix mimetics. Tetrahedron. 2016-03, 72 (9): 1151–1160 [2022-03-07]. doi:10.1016/j.tet.2015.12.044. (原始内容存档于2020-02-19) (英语). 
  4. ^ Panek (编). Category 3, Compounds with Four and Three Carbon Heteroatom Bonds: Three Carbon—Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts. Stuttgart: Georg Thieme Verlag. 2006 [2022-03-07]. ISBN 9783131187116. doi:10.1055/sos-sd-020-00065. (原始内容存档于2021-05-06) (英语).