2,2-二甲基环氧乙烷

2,2-二甲基环氧乙烷是一种有机化合物,化学式为C4H8O,它是1,2-二甲基环氧乙烷同分异构体。它在镧系金属配合物的催化下可以和二氧化碳发生环加成反应,生成 异丁烯碳酸酯。[2][3]

2,2-二甲基环氧乙烷
别名 氧化异丁烯
甲基环氧丙烷
识别
CAS号 558-30-5  checkY
PubChem 11208
SMILES
 
  • O1CC1(C)C
性质
化学式 C4H8O
摩尔质量 72.11 g·mol−1
沸点 51.5 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ House, Herbert O. The Rearrangement of Aliphatic Ethylene Oxides. Journal of the American Chemical Society (American Chemical Society (ACS)). 1955, 77 (19): 5083–5089. ISSN 0002-7863. doi:10.1021/ja01624a040. 
  2. ^ Wang, Wen-Min; Qiao, Na; Xin, Xiao-Yan; Wu, Zhi-Lei; Cui, Jian-Zhong. Octanuclear Ln(III)-Based Clusters Assembled by a Polydentate Schiff Base Ligand and a β-Diketone Co-Ligand: Efficient Conversion of CO2 to Cyclic Carbonates and Large Magnetocaloric Effect. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-19, 23 (1): 87–95. ISSN 1528-7483. doi:10.1021/acs.cgd.2c00746. 
  3. ^ Wang, Wen-Min; Cheng, Rui-Rui; Wu, Zhi-Lei; Cui, Jian-Zhong. Bifunctional Lanthanide-Based Coordination Polymers: Conversion of CO2 and Highly Selective Luminescence Sensing for Acetylacetone. Inorganic Chemistry (American Chemical Society (ACS)). 2023-08-31, 62 (37): 14902–14911. ISSN 0020-1669. doi:10.1021/acs.inorgchem.3c01626.