苯甲硒醇是一种有机硒化合物,化学式为C7H8Se,它在空气中容易氧化。[1]

苯甲硒醇
别名 苄硒醇
识别
CAS号 16645-12-8  checkY
性质
化学式 C7H8Se
摩尔质量 171.1 g·mol−1
沸点 101.5—102.5 °C(374.6—375.6 K)(22 torr)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

合成

编辑

苯甲硒醇可由氯化苄硒氢化钠反应制得[2],或二苄基二硒氢化铝锂[3]硼氢化钠[4]还原后酸化得到。

参考文献

编辑
  1. ^ 1.0 1.1 Rheinboldt, Heinrich; Giesbrecht, Ernesto. Unsymmetrical diselenides. Chemische Berichte, 1952. 85. 357-368.
  2. ^ Alfredo Ricardo Marques de Oliveira, Leandro Piovan, Fabio Simonelli, Anderson Barison, Maria de Fatima C. Santos, Murilo Belini Marcondes de Mello. A 77Se NMR study of elemental selenium reduction using NaBH4. Journal of Organometallic Chemistry. 2016-03, 806: 54–59 [2023-03-12]. doi:10.1016/j.jorganchem.2016.01.028. (原始内容存档于2018-06-28) (英语). 
  3. ^ Antonella Capperucci, Alessandra Petrucci, Cristina Faggi, Damiano Tanini. Click Reaction of Selenols with Isocyanates: Rapid Access to Selenocarbamates as Peroxide‐Switchable Reservoir of Thiol‐Peroxidase‐Like Catalysts. Advanced Synthesis & Catalysis. 2021-09-07, 363 (17): 4256–4263 [2023-03-12]. ISSN 1615-4150. doi:10.1002/adsc.202100611. (原始内容存档于2023-03-12) (英语). 
  4. ^ Ying Zhong, Xiaoming Xu, Qingzhao Xing, Song Yang, Jing Gou, Ziwei Gao, Binxun Yu. Furfuryl Cation Induced Three-Component Reaction to Synthesize Triazole-Substituted Thioesters: Furfuryl Cation Induced Three-Component Reaction to Synthesize Triazole-Substituted Thioesters. European Journal of Organic Chemistry. 2020-06-16, 2020 (22): 3251–3256 [2023-03-12]. doi:10.1002/ejoc.202000299 (英语).