丙烯基苯是一种有机化合物,化学式为C9H10,是烯丙基苯同分异构体。它的催化加氢反应可以得到正丙基苯[5];它和偏高碘酸钠反应,得到苯甲醛[6]

丙烯基苯
识别
CAS号 637-50-3  checkY
766-90-5(顺式)  checkY
873-66-5(反式)  checkY
PubChem 252325
SMILES
 
  • CC=CC1=CC=CC=C1
UN编号 2618
RTECS DA8400500
性质
化学式 C9H10
摩尔质量 118.18 g·mol−1
外观 无色液体
密度 0.911 g/cm3
熔点 −60.5—−59.0 °C(212.7—214.2 K)(顺式)[1]
−29.3 °C(243.8 K)(反式)[2]
沸点 167 °C(440 K)(顺式)[3]
175 °C(448 K)(反式)[4]
危险性
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中易燃物的标签图案
GHS提示词 警告
H-术语 H225, H226
P-术语 P210, P233, P240, P241, P242, P243, P280, P303+361+353, P370+378, P403+235, P501
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ W. R. R. Park, George F Wright. OXYMERCURATION OF cis- AND trans-PROPENYLBENZENE. The Journal of Organic Chemistry. 1954-09, 19 (9): 1435–1443 [2021-06-29]. ISSN 0022-3263. doi:10.1021/jo01374a005 (英语). 
  2. ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-29].
  3. ^ Brudnik, I. M.; Shornikov, D. V.; Bresler, I. G.; Akhmatdinov, R. T.; Kantor, E. A.; Rakhmankulov, D. L. Reaction of dimethoxymethane with styrene and its methyl derivatives(俄文). Zhurnal Organicheskoi Khimii, 1989. 25 (4): 814-818. ISSN: 0514-7492.
  4. ^ Rocca, Andre. Aralkanoyl aliphatic ketones. 1966. FR 1457540.
  5. ^ Tim N. Gieshoff, Matteo Villa, Alice Welther, Markus Plois, Uttam Chakraborty, Robert Wolf, Axel Jacobi von Wangelin. Iron-catalyzed olefin hydrogenation at 1 bar H 2 with a FeCl 3 –LiAlH 4 catalyst. Green Chemistry. 2015, 17 (3): 1408–1413 [2021-06-29]. ISSN 1463-9262. doi:10.1039/C4GC02368D (英语). 
  6. ^ Thimma Sambamoorthy Manikandan, Rengan Ramesh, David Semeril. Synthesis and characterisation of cycloruthenated benzhydrazone complexes: catalytic application to selective oxidative cleavage of olefins to aldehydes. RSC Advances. 2016, 6 (99): 97107–97115 [2021-06-29]. ISSN 2046-2069. doi:10.1039/C6RA19044H (英语).